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Extracting rose essential oil from rose slag with ionic liquid

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Abstract

Twelve ionic liquids were synthesized and used as solvents to extract rose essential oil from rose slag. Tetrabutylammonium bromide propionic acid ionic liquid was selected as the best solvent. Five factors (feed to liquid ratio, extraction temperature, reflux time, stripping agent amount, and repeated extraction times) were considered in the reaction. The results showed that the optimum process conditions were 1:4 mass ratio of material to liquid, the temperature 75 °C, reflux time 4 h, and the amount of stripping agent 100 g; the highest yield of essential oil is 1.6095%. The yield did not show an obvious decline after repeating extraction three times. Comparing the yield, solvent consumption, and extraction time with other organic solvents, using tetrabutylammonium bromide propionic acid ionic liquid can effectively reduce energy and reduce environmental burden, which proves that the technology is sustainable.

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References

  1. Hur MH, Song JA, Lee J, Lee MS (2014) Aromatherapy for stress reduction in healthy adults: a systematic review and meta-analysis of randomized clinical trials. Maturitas 79:362–369

    Article  Google Scholar 

  2. Mahboubi M (2016) Rosa damascena as holy ancient herb with novel applications. Tradit Complement Med 6:10–16

    Article  Google Scholar 

  3. Nowak R, Olech M, Pecio Ł, Oleszek W, Los R, Malm A, Rzymowska J (2014) Cytotoxic, antioxidant, antimicrobial properties and chemical composition of rose petals. J Sci Food Agric 94:560–567

    Article  Google Scholar 

  4. Weekly I (2008) Rose Bengal sodium promising in malignant melanoma. Biomass Conversion and Biorefinery 1660:9

    Google Scholar 

  5. Ulusoy S, Bosgelmez-Tinaz G, Secilmis-Canbay H (2009) Tocopherol, carotene, phenolic contents and antibacterial properties of rose essential oil, hydrosol and absolute. Curr Microbiol 59:554–558

    Article  Google Scholar 

  6. Nayebi N, Khalili N, Kamalinejad M, Emtiazy M (2017) A systematic review of the efficacy and safety of Rosa damascena Mill. with an overview on its phytopharmacological properties Complement. Ther Med 34:129–140

    Google Scholar 

  7. Mohebitabar S, Shirazi M, Bioos S, Rahimi R, Malekshahi F, Nejatbakhsh F (2017) Therapeutic efficacy of rose oil: a comprehensive review of clinical evidence Avicenna. Phytomed 7:206–213

    Google Scholar 

  8. Du FY, Xiao XH, Li GK (2009) Application of ionic liquids in the microwave-assisted extraction of polyphenolic compounds from medicinal plants. Talanta 78:1177–1184

    Article  Google Scholar 

  9. Rezaee M, Assadi Y, Milani Hosseini MR, Aghaee E, Ahmadi F, Berijani F (2006) Determination of organic compounds in water using dispersive liquid-liquid microextraction. Chromatogr A 1116:1-9, 1.

  10. Zhang LY, Cao BC, Yao D, Yu RZ, Yu CQ, Zhang HQ, Yu AM (2015) Separation and concentration of sulfonylurea herbicides in milk by ionic-liquid-based foam flotation solid-phase extraction. Sep Sc 1217:4241–4246

    Google Scholar 

  11. Li N, Zhang R, Nian L, Ren RB, Wang YQ, Zhang HQ, Yu AM (2012) Extraction of eight triazine and phenyl urea herbicides in yogurt by ionic liquid foaming-based solvent floatation. Chromatogr A 1222:22–28

    Article  Google Scholar 

  12. Earle MJ, Seddon KR (2000) Ionic liquids. Green solvents for the future. Pure Appl Chem 72:1391–1398

    Article  Google Scholar 

  13. Low FW, Samsudin NA, Yusoff Y, Tan XY, Lai CW, Amin N, Tiong SK (2020) Hydrolytic cleavage of glycosidic bonds for cellulose nanoparticles (CNPs) production by BmimHSO 4 ionic liquid catalyst. Thermochim Acta 2020:684

    Google Scholar 

  14. Szalaty TJ, Klapiszewski Ł, Jesionowski T (2020) Recent developments in modification of lignin using ionic liquids for the fabrication of advanced materials-a review. J Mol Liq 301:112417

    Article  Google Scholar 

  15. Collin HA (2003) Extraction and industrial processes. Encyclopedia of Rose Science:726–735

  16. Olmedo R, Nepote V, Grosso NR (2014) Antioxidant activity of fractions from oregano essential oils obtained by molecular distillation. Food Chem 156:212–219

    Article  Google Scholar 

  17. Reverchon E (1997) Supereritical fluid extraction and fractionation of essential oils and related products. Supereritical Fluids 10:1–37

    Article  Google Scholar 

  18. Babu KGD, Singh B, Joshi VP (2002) Essential oil composition of Damask rose ( Rosa. damascena Mill. ) distilled under different pressures and temperatures. Flav Fragr J 19(2):136–140

    Article  Google Scholar 

  19. Lin ZH, Lin B, Zhang XC, Guo JE (2019) Research progress on extraction process of volatile oil from Artemisia argyi. Yunnan Chemical Industry 46:56–59

    Google Scholar 

  20. Zhang Q (2018) Research progress of extraction technology and application of rose essential oil. Contemporary Chemical Research:153–154

  21. Yang M (2019) Extraction process of thyme essential oil. Tropical Agricultural Science 39:88–92

    Google Scholar 

  22. Zheng HF, Liao SL, Fan GR, Si HY (2019) Research progress of development and utilization of linal essential oil. Guangzhou Chemical Industry 47:17–19

    Google Scholar 

  23. Vekariya RL (2017) A review of ionic liquids: applications towards catalytic organic transformations. Mol Liq 227:44–60

    Article  Google Scholar 

  24. Trivedi TJ, Kumar A (2011) Efficient extraction of agarose from red algae using ionic liquids. Green and Sustainable Chemistry 57:1344–1355

    Google Scholar 

  25. Fu-You D, Xiao X-H, Luo X-J, Li G-K (2009) Application of ionic liquids in the microwave-assisted extraction of polyphenolic compounds from medicinal plants. Talanta:78

  26. Olivier-Bourbigou H, Magna L, Morvan D (2010) Ionic liquids and catalysis: recent progress from knowledge to applications. Appl Catal A Gen 373:1–56

    Article  Google Scholar 

  27. Zhuang B, Dou LL, Li P, Liu EH (2017) Deep eutectic solvents as green media for extraction of flavonoid glycosides and aglycones from Platycladi Cacumen. Pharm Biomed Anal 134:214–219

    Article  Google Scholar 

  28. Gao J, Fang CL, Lin YZ, Nie FH, Ji HW, Liu SC (2020) Enhanced extraction of astaxanthin using aqueous biphasic systems composed of ionic liquids and potassium phosphate. Food Chem 309:125672

    Article  Google Scholar 

  29. Yue D, Jia Y, Yao Y, Sun Y, Jing Y (2012) Electrochim Acta 65:30–36

    Article  Google Scholar 

  30. Maciąg A,Kalemba D (2015) Composition of rugosa rose ( Rosa rugosa thunb.) hydrolate according to the time of distillation. Phytochemistry Letters 11.

  31. Li N, Wang Y, Xu K, Huang Y, Wen Q, Ding X (2016) Development of green betaine-based deep eutectic solvent aqueous two-phase system for the extraction of protein. Talanta 152:23–32

    Article  Google Scholar 

  32. Reverchon E (1997) Supercritical fluid extraction and fractionation of essential oils and related products. Journal of Supercritical Fluids 1-37

  33. Reverchon E, Porta GD (1996) Rose concrete fractionation by supercritical CO2. J Supercrit Fluids 9:199–204

    Article  Google Scholar 

  34. Yu H, Ma WP, Liu YP, Li JX, Liu JM (2015) Analysis of volatile components in essential oils of peony flowers by headspace-Gas chromatography-mass spectrometry. Food Sci 36:167–171

    Google Scholar 

  35. Du LJ, Zheng GT, Niu XQ, Lin XH, Zhang TQ (2015) Analysis of factors affecting the extraction of essential oil from pepper leaves by solvent extraction. Fujian Hot Work Technology 40:42–44

    Google Scholar 

  36. Gao HK, Sun JC, Hou LL, Xu GC, Zhang H (2018) Study on the extraction of peach blossom essential oil by ethanol method and analysis of the components of peach blossom essential oil. Biol Res 40:182–185

    Google Scholar 

  37. Xu SQ, Li XD, Zhang JG (2013) Comparative analysis of quality and composition of tissue cultured thyme essential oil extracted by different methods. Journal of Plant Science 31:609–615

    Article  Google Scholar 

  38. Greaves TL, Drummond CJ (2008) Protic ionic liquids: properties and applications. Chem Rev 108:206–237

    Article  Google Scholar 

  39. Anderson JL, Ding J, Welton T (2002) Characterizing ionic liquids on the basis of multiple solvation interactions. J Am Chem Soc 124(47):14247–14254

    Article  Google Scholar 

Download references

Funding

This study was financially supported by the National Natural Science Foundation of China (No. 21106032)

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Authors and Affiliations

  1. College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang, 050018, People’s Republic of China

    Changchang Guo, Juan Zhang, Chaozheng Liu, Yuhang Bian & Qingwen Shan

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  1. Changchang Guo
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  2. Juan Zhang
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  3. Chaozheng Liu
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Correspondence to Juan Zhang.

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Guo, C., Zhang, J., Liu, C. et al. Extracting rose essential oil from rose slag with ionic liquid. Biomass Conv. Bioref. 12, 2305–2312 (2022). https://doi.org/10.1007/s13399-020-00751-9

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